摘要:The evolution behavior of cluster and subsequent precipitation in Al-Si-Cu-Mg alloys during aging procss were analyzed by means of three dimensional atom probe(3DAP)and first-principles calculations.3DAP experiment shows that dot-like Si-Si clusters,Si-Mg clusters and Si-Mg-Cu clusters appear in Al-1.0Si-1.5Cu-0.5Mg alloy with aging at 175℃for 0.25 h.First-principles calculation shows that the strong interaction exists between the solute atoms in structures mentioned.It consistents with the3 DAP experimental results.Meanwhile,the diffusion of Si atoms with a large number leads to the generation of Si-Cu clusters.As Si,Mg,Cu atoms continued to precipitation with aging for 0.25h2h,dot-like Si-Si clusters,Si-Cu clusters,Si-Mg clusters are grown into needle-like Si-Mg-Cu clusters.In further aging evolution,the aggregation of Si,Mg,Cu atoms promotes the growth of Si-Mg-Cu structures,and some Si-Mg-Cu structure is converted into lath-like Q′phase with generation of the Cu-rich structure.
摘要:NiTiCu shape memory alloys were prepared by conventional tungsten arc-melting technique.The metallographic morphologies,phase constituent,wettability,microhardness and corrosion resistance of the NiTiCu ingots prepared were investigated by optical microscope,X-ray diffraction(XRD),contact angle tester and microhardness tester.The results show that the NiTiCu alloys are composed of B2 austenite phase and B19′martensite phase,and the diffraction intensity of the B19′martensite phase is increased with increasing in the contents of Cu.The NiTiCu ingots exhibit typical as-cast metallography,such as bulky equiaxed crystals at the center of ingot,the small equiaxed crystals at the edge and columnar crystal at the middle.The contact angle of the NiTiCu alloys is increased with increasing in the contents of Cu.At the same time,the microhardness of the NiTiCu alloys is decreased.The Cu contents have a little positive effect on the corrosion resistance of NiTiCu alloys in the artificial saliva.
摘要:The Ti35Zr30Be27.5-xCu7.5Cox(x=3.5%,7.5%,11.5%)bulk amorphous alloys rods with 12 mm in diameters were prepared by copper mold casting method.Effects of Co content on the structure,glass-forming ability and thermal stability were investigated using X-ray diffractometer(XRD)and differential scanning calorimeter(DSC).The results show that with the substitution of Co for Be,glassforming ability(GFA)is significantly enhanced and amorphous rods with a diameter of up to 12 mm are produced with 3.5%and 7.5% Co.With increasing the Co content from 7.5%to 11.5%,the GFA is sharply declined to less than 5mm.However,the glass transition temperature,Tg,and the crystallization temperature,Tx,of Ti35Zr30Be27.5-xCu7.5Cox(x=0,3.5%,7.5%,11.5%)alloys are decrease from 636 Kand 718Kto 612 Kand 647K,respectively.Effects of Co addition on the structure of the Ti35Zr30Be27.5-xCu7.5Cox(x=0,3.5%,7.5%,11.5%)alloys were described.
摘要:Effects of filler content(iron powder and aluminum powder)on the mechanical properties of the E-44 epoxy resin were investigated.The results indicate that the compression strength and the tensile strength of the resin materials reach 80 MPa and 2730MPa,respectively,with iron powder to E-44 resin of(34.2)∶1and aluminum powder to E-44of(23.2)∶1,meeting the strength requirement of common ejection mold.The strength of filler material is decreased with the mass ratio of filler content and E-44 epoxy resin increase.
关键词:Iron Powder;Aluminum Powder;Filler;Resin Material
摘要:Silica granules have good wettability to silicon melt,and could be used as seeds to grow fine and well-distributed columnar silicon grains for high-performance multi-crystalline silicon(MC-silicon)related with high conversion efficiency of the solar cells.Si3N4 was coated to the silica granules for improving the MC-silicon growth and ingot releasing effect.It is found that the Si3N4 coating on the silica granules is helpful for obtaining fine and uniformly distributed columnar grain to decrease the defect density and improve the quality of multi-crystalline silicon.In addition,the detachment of the silica granules from silicon ingot is realized easily to eliminate the stress from the bonding of multi-crystalline silicon with silica granules.
摘要:Effects of Ti、V、Nb、Mo on the morphology,hardness and impact toughness of carbides in high Cr alloy containing 2.8%carbon and 31.0%chromium were investigated.The results show that with the increase of alloy contents,the carbides size is gradually refined firstly and then coarsened,and hardness and impact toughness are increased firstly and then decreased.When the amounts of alloy elements are 0.4%Ti、0.4%V、0.4%Nb、0.35%Mo,the hardness and comprehensive mechanical properties exhibit desirable,where hardness and impact toughness reach up to 58.9HRC and 11J·cm-2,respectively.
摘要:Semi-solid 2024 aluminum alloy billet was prepared by recrystallization and partial remelting technology.Microstructure evolution was observed at different remelting temperature and holding time,and effects of processing parameters on grain size and spheroidization rate were analyzed.Based on thixo-forming casting,the difference of mechanical properties was described at varied position on the samples with different billet height.The results show that microstructure of the billet gradually undergoes the disappearance of extruded fibrous tissue,the generation ofα-Al recrystallized grains and the spheroidization and growth ofα-Al grains with increasing in holding time,and the process is accelerated with the remelting temperature increase.The size and spheroidization rate of the semi-solid grains are increased with the increase of remelting temperature and holding time.The average grain size with approximately 75μm and spheroidized rate of 0.74 can be obtained at 613621℃for 2030min,and the tensile strength of the thixoforming parts can be reached up to 383 MPa.The tensile strength exbibits greatly different at different position due to the parts shape and forming characteristics.
关键词:2024 Alloy;Recrystallized and Remelting Method;Structure Evolution;Thixoforming
摘要:Effects of compound modification and isothermal heat treatment on microstructure and properties of in-situ Mg2Si/Al composites were investigated by compound modification of P and mischmetall and adjusting the insulation temperature and holding time of semi-solid isothermal treatment.The results indicate that after P and mischmetall compound modification,the massive cross-shaped morphology of Mg2 Si primary phase in the composites is transformed into irregular polygons,which are uniformly distributed in Al substrates.The average size of primary phase is decreased from about 83μm before modification to about 17μm.The morphology of Mg2 Si primary phase andα-Al phase is transformed into near-spheric shape after semi-solid isothermal treatment at 570℃for 90 min,and the shape factor of Mg2 Si primary phase reaches up to approximately 0.96 with an average size of about 16μm.Meanwhile,the brinell hardness of the composites reaches a maximum of 106 HB.
摘要:Semi-solid microstructural evolution of extruded Mg-5.5Zn-2Gd-0.6Zr magnesium alloy with different extrusion ratio by the SSIMA process was investigated.It is found that the relationship between the average diameter ofα-Mg grains and the isothermal holding time meets the difference between the cube of average grain diameter and initial average grain diameter equal to the coarstning constant K and the isothrmal time t under the condition of the same extrusion ratio.The coarsening rate constant K is decreased with the increase of the extrusion ratio,which reaches 359μm3/s,289μm3/s and 266μm3/s when the extrusion ratio is 10,15 and 30,respectively.It is also found that the semi-solid isothermal evolution process of the experimental alloy is accelerated with the increase of the extrusion ratio,meanwhile,the roundness and uniformity ofα-Mg grains also are improved.
摘要:The roller manufactured by liquid die forging technology was conducted.And according to the theory of materials mechanics and solidification,the quantitative calculation model of the start-pressure time and the hold-pressure time of liquid die forging rollers was derived.Meanwhile,combining with the working principle of the liquid die forging technology of rollers,the pouring height of rollers during squeezing casting process was presented,and its computation formula was given.Through ProCAST to analysis the roller with the specification175mm×480mm and the verification test of smaller sample of the roller,absence of defects such as shrinkage cavities and porosities in the squeezing casting roller can be observed.
关键词:Liquid Die Forging;Roller;Start-Pressure Time;Hold-Pressure Time;Pouring Height
摘要:Based on Power-Cutoff model,using ProCAST casting simulation software,the die-casting process for magnesium alloy gearbox case at liquidus and semi-solid temperature region was analyzed.By orthogonal experiments,effects of plunger injection speed,casting temperature,mold temperature and the heat transfer coefficient between die mold and die castings on the defect rate were visualized,and the processing parameters were optimized.The results reveal that injection velocity on the maximum defect rate in die casting can be neglected,while lower injection speed can greatly reduce the total casting defect rate with ingate velocity between 4090m/s.Moreover,both the maximum and total casting defect rate can be significantly reduced with semi-solid casting temperature,higher mold temperature and lower heat transfer coefficient between die mold and castings.The optimized processing parameters were presented as follows:the plunger injection speed of 5m/s,pouring temperature of 570℃,mold temperature more than 200℃and heat transfer coefficient between die mold and castings of 500W/(m2·K).
摘要:It is a key factors of good spraying of mould lubricant for obtaining excellent surface quality of the castings.However,the used spraying techniques could not cover the whole surface of the mould,leading to the occurrence of poor spraying effects,partial soldering and pull-failure.Through adopting inner-spraying technology,the problems can be eliminated effectively.The inner-spraying apparatus is composed of spraying channel designed in the mould and an atomizer,exhibiting the features of fully utilizing the pipeline and control unit on the die casting machine.Atomizer directly connect with coating pipe and gas pipe on spraying robot in one end,and connect with inlet of inner-sprayed channel in the mould in other end,realizing the synchronous operation with spraying robot on the die casting machine.The practical verification reveals that the inner-spraying technique can greatly decrease the scrap rate of the die castings.
摘要:The low pressure casting process for thin-walled Al alloy shell as a crucial structural component was designed,and the filling flow pattern,temperature field and shrinkage porosities(holes)in thin-walled aluminum alloy shell were simulated to optimize the low pressure casting process.The simulated results show that with copper core instead of steel core,the stable filling flow and uniform temperature distribution can be visualized,and the shrinkage porosities(holes)are visualized to be distributed out the shell.The optimized casting process can optimize effectively temperature field and reduce the possibility of shrinkage holes(porosities),obtaining the qualified shell with high quality.
关键词:Thin-Walled Al Alloy Shell;Numerical Simulation;Temperature Field;Shrinkage Porosity
摘要:Different protective methods of the gypsum mold for gravity casting of magnesium alloy were analyzed comparatively.The results show that manufacturing process by using borate and gypsum powder mixed protection is simple,however,it may affect cure of gypsum slurry.By using manufacturing process of watering borate after mold baking,the oxidation on casting surface exhibits serious.Manufacturing process by watering borate after borate and gypsum powder mixing baking exhibits the oxidation-free and desirable ignition-proof efficiency,however,due to increasing procedure,the method is only suitable for the small batch of production of magnesium alloy parts.
摘要:The comparison sampling,measurement and analysis of full mold lost foam EPS products pattern outer surface,inner surface of coating layer shell and outer surface of cast iron products were processed with the help of non-contact 3Droughness profile optical analyzer.Evaluation length for sampling was set to 14.623 mm,and assessment area for sampling was set to 1.703 1cm2,and cast iron surface profile roughness critical value Lc(cut of wavelength)was set to 800μm.Measurement data shows that the average line roughness value Rareaches 10.717 1μm,5.846 3μm and 5.923 5μm,respectively,and the average surface roughness value Sareaches 17.500 4μm,9.476μm and 10.139 8,respectively.The inner surface roughness physical characterization of the coating layer shell is more relative with full mold lost foam casting,which may directly affect the surface roughness values.The effects influence of coating room temperature contact angle and liquid metal high-temperature contact angle on EPC casting surface roughness were analyzed.
摘要:Characteristic of duplex stainless steel,dimensional parameter of sleeves and centrifugal casting technique were described.Key points in preventing crack,double skin and air hole were presented.Through decreasing centrifugal speed,it is effective for preventing hot crack,however,heat reserving capacity of the mould should be improved to prevent liquid alloy from overflowing.During solidification process of 1.4460 duplex stainless steel,rotating speed could be further decreased.Meanwhile,increasing pull-mold temperature,hot crack could be relieved.Through increasing mould temperature,adopting conch gate with analogy gradation section and controling initial pouring speed to meet initial thickness,double skin in castings such as cast steel jacket with small caliber could be eliminated.
关键词:Duplex Stainless Steel;Centrifugal Casting;Sleeves With Small Caliber;Defect Prevention
摘要:A three-dimensional flow,heat transfer and solidification coupling mathematical model of ultrathick slab mold was established.According to the actual working condition of slab,effects of the width and thickness change of ultra-thick slab mold on flow and temperature field in mold were analyzed.The results show that with the increase of width of the mold,impacting depth of the liquid steel on the shell is increased and impacting intensity is weaken.Compared with continuous casting conventional slab,liquid surface velocities of the ultra-thick slab are decreased,and then it is decreased with increasing in mold width.In addition,there exists a low flow velocity zone at the nozzle,which is harmful for the protective slag melting.With the increase of mold width,shell thickness tends to uniform.Impact strength of liquid steel at the center is the main reason affecting the uniformity of the shell.With the increase of thickness,impact on the shell of narrow side and velocities of the liquid surface is weaker,while depth of impingement keeps constant.With the increase of thickness,shell heterogeneity becomes serious.The uniformity of the shell is controlled by uniformity of temperature field.
摘要:Based on the finite element method,temperature field in casting process the 1st round billet casting machine from the Baotou Steel company were analyzed to find a proper location for positioning the final electromagnetic stirring(F-EMS)stirrer.Through applying transient magnetic field analysis method,the distribution of magnetic flux density and electromagnetic force in the bloom during stirring process was analyzed,and process parameters of F-EMS were optimized.With a casting speed velocity of 0.45m/min,specific water flow of 0.18L/kg and superheat value degree of 25℃,the optimized electric stirring parameters for round bloom with 430 mm in diameters were presented as follows:current of 250 A,frequency of 10 Hz.Magnetic flux density in the stirrer under no-load was measured.The results were well in agreement with simulated ones.
摘要:The fine grained Cu-Sn and Cu-Sn-Fe alloys were prepared in a copper mould with a high cooling rate,and effects of Sn and Fe compound alloying on the tensile strength of casting and rolling Cu-SnFe were investigated.The results show that the tensile strength of Cu-Sn-Fe can be increased markedly by compound alloying and rolling.The mechanism of compound alloying and rolling was described.
摘要:Effects of magnetic field and intensity of electromagnetic stirring on solidification structure and macro-composition segregation of Pb-80 Sn cast ingots were investigated.The results show that spiral magnetic field has a better effect in improving the solidification structure and macro composition segregation through promoting a large zone stirring for alloy melt to make the solute and temperature field distribution more uniform.At a fixed frequency,the solidification structure exhibits desirable when the current is 125 Afor rotating magnetic field and 100 Afor spiral magnetic field,where the grain sizes are reduced to 152.6μm and 143.2μm from 247.5μm without magnetic field,respectively.The composition segregation is relieved greatly when the current is 125 Afor both rotating and spiral magnetic field,reduced to 1.37%and 0.28%from 9.71%in the absence of magnetic field,respectively.
关键词:Magnetic Field Intensity;Solidification Structure;Pb-80Sn Hypereutectic Alloy
摘要:The wettability and interfacial reactions between Sn-0.7Cu solder and Cu substrate were investigated under thermoelectric coupling field.Effects of different current density in range of 1.54.5A and temperature in range of 250350℃as well as polarity of the Cu substrate on wettability and interfacial reaction between Sn-0.7Cu solder and Cu substrate were investigated by measuring wetting angles and observing sectional morphology of the series samples prepared.The results indicate that at fixed other processing parameters,the wettability between Sn-0.7Cu solders and the Cu substrates can be improved with temperature increase,and the increasing of the current can decrease the wettability angles.In addition,the substrate as anode also can improve the wettability.
摘要:H65,BZn18-26 and QSn6.5-1scraps were used to prepare lead-free free-cutting Si brass to substitute for HPb59-1.Effects of Si on the structure of brass prepared were investigated.The results show that the Si content in the brass is related obviously with the microstructure of the brass.With the Si content of 0.2%0.6%in the alloy,the alloy is composed ofαphase in board strips shape mainly andβphase,and the amount ofβphase is increased with the increase of Si content.When Si content is0.8%,the matrix isβphase in polygon,andαphase is distributed in grains and boundary.When Si content is 1.0%,the matrix isβphase with a large number of phases in small particle and blocks.It is speculated according to the atomic percentage that the phases belong to composites Cu5Si+βor Cu2Mg+βin tiny granular,and with the increase of Si content,small granular phase is increased significantly.
摘要:Using carbon steel(0.45%C)as matrix,and high carbon ferrochrome as cast-infiltration agent,the steel-based surface composites were fabricated by conventional cast-infiltration process combined with the thermite reaction.Influences of various processing parameters such as pouring temperature,the placement location,the content of aluminum and the binder on formation of cast-infiltration layers were investigated.The results show that the interfacial bonding belongs to metallurgical fusion between cast-infiltration layer and the matrix,and the cast-infiltration composites mainly consist of M7C3,Cr7C3,Al2O3,when the pouring temperature is 1 650℃.The high-quality cast-infiltration composite layer can be prepared with the preforms embedded in the lower part of the mold wall.The desirable surface quality of cast-infiltration layer can be obtained without any binder.
摘要:The wear behavior at high temperature of Al2O3 ceramic reinforced 20Cr25Ni20 matrix composites prepared by squeeze casting at 500℃ were investigated,and it was compared with the matrix material 20Cr25Ni20 and other several common roll materials.The results reveal that the Al2O3p/20Cr25Ni20 composites exhibit a better wear resistance,with the specific pressure of 7.95 MPa,which is about 3.4times higher than the matrix materials,and higher than Cr25 high chromium cast iron by 46%.However,the wear resistance of YG10 cemented carbide is 6.5times higher than Al2O3p/20Cr25Ni20 Composites.The matrix materials present serious plastic flow and cutting after high temperature wear,while Al2O3 ceramics plays a good role as the abrasion phase.
关键词:Heat-Resistant Steel Matrix Composites;High Temperature Wear;Roll Material
摘要:A biomedical Ca/P film on pure Ti was prepared by micro-arc oxidation in the Ca/P electrolyte systems with different concentration.The surface micro-topography and 3-D morphology were observed by SEM and HIROX.The relationship of porosity ratio,density,size and 3-D morphology with electrolyte concentration was investigated under the condition of the given Ca/P ratio electrolyte.The results show that with the electrolyte concentration increase,the thickness is increased and the porosity ratio,pore size as well as pore density are decreased.In low concentration,the surface of the film exhibits more crater-like porous structure,however,in high concentration,the porous structure is formed by the sintering process of melt repeatedly.Effects of NaOH concentration on the ceramic film is more important.
摘要:The corrosion behavior of Mg-15 Y magnesium alloy after aging at different temperature and time in 3.5% NaCl solution was investigated,and corrosion mechanism of the alloy was described.The results show that the peak aging time of Mg-15 Yis 12hat 225℃,where the hardness of the alloy reaches the maximum values.And then with increasing in aging time,the hardness of the alloy is decreased to approximately 110.The corrosion depth and the hydrogen evolution are gradually increased with increasing in soaking time.At a fixed soaking time,the corrosion degree and the hydrogen evolution rate are increased firstly and then decreased with increasing in soaking time,while the corrosion potential and corrosion current of the alloy are decreased firstly and then increased.At the same temperature,corrosion morphology change can be neglected with postponing aging time,however,hydrogen evolution rate is decreased firstly and then increased.
摘要:Filling,solidification and stress formation in process of trial-producing AC7 Aaluminum alloy frame were simulated by the ADSTEFAN software to solve the practical problems.The results reveal that the severe heterogeneous flow in ingate take a dramatically temperature distribution difference in the frame to lead to the generation of severe casting stress and strain,which is responsible for the crack occurrence.Based on the simulated result,casting parameters were optimized to realize more rational pouring and solidification process,and equivalent stress and strain are decreased by 10%and 20%,respectively,eliminating the hot crack defects in the AC7 Aaluminum alloy frame.
摘要:Abnormal mechanical properties of forged 6061 wrought aluminum alloy wheel could be analyzed after T6 heat treatment.Effects of different working stages and T6 treatment on mechanical properties of the wheel were analyzed.In addition,the origination of abnormal mechanical properties was described.The countermeasures of eliminating abnormal mechanical property data were presented through adjusting heat treatment processes.
摘要:The casting process for small batches of V12 aluminum engine block was developed.The technical problems and operation challenges including handmade complex geometry sand core,position structure for big size sand core,gate and riser design,and so on,were solved successfully.The developed process is suitable for the manufacturing V12 aluminum engine block.
摘要:2024aluminum alloy with Ag-free is an important precipitation strengthened alloys.TheΩphase can be precipitated by cold rolled at room temperature and duplex ageing.The precipitation mechanisms ofΩphase in 2024 aluminum alloy was explored by transmission electron microscopy(TEM),energy spectrum analysis and other methods.The results demonstrate that duplex ageing and cold rolled technigue are the effective process to promote the precipitation ofΩphase.The concentration decrease of Mg and a large number of nucleation sites around Tphase are mainly responsible for the precipitation ofΩphase.