Yu Baobiao, Yan Hong, Liu Jianlong, et al. Effects of La on the Microstructure and Corrosion Behavior of ADC12 Alloy[J]. Special Casting & Nonferrous Alloys, 2019,39(3):335-338.
Yu Baobiao, Yan Hong, Liu Jianlong, et al. Effects of La on the Microstructure and Corrosion Behavior of ADC12 Alloy[J]. Special Casting & Nonferrous Alloys, 2019,39(3):335-338. DOI: 10.15980/j.tzzz.2019.03.026.
La对ADC12微观组织及耐腐蚀性能的影响
摘要
采用光学显微镜、扫描电镜、能谱仪等研究了ADC12-xLa(x=0
0.3
0.6
0.9)合金的微观组织及腐蚀性能。结果表明
当La含量从0增加到0.6%时
ADC12合金中的初生α-Al、共晶Si和Al
8
SiFe
2
相会逐渐细化
且耐腐蚀性能逐渐提高。其原因是La含量低于0.6%时
La在变质过程中会吸附在共晶Si相表面
阻碍了腐蚀电子流动
使合金的耐腐蚀性能提高。而La含量达到0.9%时
合金中会生成大量的La-Al-Cu稀土相
该稀土相会与α-Al发生电偶腐蚀
导致ADC12-0.9La合金耐腐蚀性能降低。
Abstract
The effects of La on the microstructure and corrosion behavior of ADC12-xLa(x=0
0.3
0.6
0.9)alloy were investigated by optical microscope(OM)
scanning electron microscope(SEM)and energy disperse spectrometer(EDS).The results show that when La content is increased from 0 to 0.6%
the morphology of primaryα-Al
eutectic Si and Al
8
SiFe
2
phases in the ADC12 alloy is refined gradually and the corrosion resistance is improved gradually.When rare earth La is less than 0.6%
it can be adsorbed at the surface of cathode phase during the modified process
thus forming a layer of rare earth oxidation film between the cathode and the anode.The rare earth oxidation film hinders the flow of corrosion electrons and improves the corrosion resistance of the ADC12 alloy.When the La content reaches 0.9%
a large amount of La-Al-Cu phases are generated in the alloy
which acts as a cathode phase in the alloy
resulting in the decrease of corrosion resistance of ADC12-0.9 La alloy.