Zhang Guang’an, Zhao Rongda, Zhang Wenfeng, et al. Formation Mechanism of Ordered Phase in Fe-24Al-C-Mn Alloys[J]. Special Casting & Nonferrous Alloys, 2017,37(12):1298-1300. DOI: 10.15980/j.tzzz.2017.12.006.
Fe-24Al-C-Mn合金中有序相形成机理研究
摘要
对Fe-24Al合金进行C和Mn的双元素合金化
利用金相、SEM、XRD和激光共聚焦显微镜研究合金铸态的组织及其形成机理。结果表明
铸态组织由α-Fe、FeAl、Fe
3
Al及Fe
3
AlC相组成。组织中存在富Al相和富C相。随着C和Mn元素的加入
合金的硬度(HV)从280增加到330
抗拉强度从400 MPa增加到741 MPa
断裂方式从完全的脆性转变为略有塑性。当加热温度为625℃时
两种白色富集相变得较为清晰
同时细小富集相的数量增加。随着温度进一步升高
合金中条状和块状白色富集相的数量显著减少
有序相固溶到基体中
当温度高于1 100℃时
合金局部组织出现轻微的氧化现象。
Abstract
In order to improve the brittleness of Fe-24 Al alloy
the alloying of C and Mn elements duplex was adopted
and the microstructure
phase structure and formation mechanism of the alloying Fe-24 Al alloy were investigated by the metallographic
SEM
XRD and confocal laser scanning microscopy.The results show that the phase structure is composed ofα-Fe、FeAl、Fe
3
Al and Fe
3
AlC phase
in which Alenrichment and C-enrichment phase can be observed.The hardness and strength of the alloys are increased from 280 HV
400 MPa to 330 HV
741 MPa
respectively
and the fracture modes are changed from brittle fracture to a fewer ductility fracture.The confocal laser scanning microscopy indicates that two kinds of white-enriched phases become cleaner
and the number of fine-enriched phases is increased.With the further increase of the temperature
the number of the white bulk and strip rich phases is decreased
and the ordered phases is dissolved into the matrix.When the temperature is the higher than1 100 ℃
the local oxidation phenomenon is presented in microstructure of the alloy.