Ren Bo, Zhang Tianqmg, Liu Zhongxia, et al. Influence of Sb on Microstructure on In-situ Mg2Si/Al-Si Composites[J]. Special Casting & Nonferrous Alloys, 2006,(12):819-821.
Ren Bo, Zhang Tianqmg, Liu Zhongxia, et al. Influence of Sb on Microstructure on In-situ Mg2Si/Al-Si Composites[J]. Special Casting & Nonferrous Alloys, 2006,(12):819-821.DOI:
Sb对原位Mg2Si/Al-5Si复合材料显微组织的影响
摘要
研究了Sb含量对Mg2Si/Al-5Si复合材料显微组织的影响。结果表明
随着Sb含量的增加
初生Mg2Si颗粒形貌明显发生了细化
Mg2Si形态由变质前的汉字体和枝晶状变为细小的、均匀分布的颗粒状
Mg2Si体积分数也有所增加。当Sb含量为0·4%时
细化效果达到最佳
由变质前的52μm变为25μm。当Sb含量超过0·4%后
Mg2Si颗粒尺寸开始粗化
因此
过量的Sb对Mg2Si颗粒的细化无益。Sb对Mg2Si颗粒的细化主要由于AlSb引起的异质形核作用
Sb使液相线温度和熔体表面张力σLV降低
对Mg2Si颗粒的细化也具有一定的作用。
Abstract
Influence of Sb on microstructure of 20 Mg2Si/Al-Si composites has been described. The results show that with the increase of Sb addition
primary Mg
Si phase is remarkably refined
in which chi-nese script or dendritic Mg2 Si phase is converted into uniformly distributed fine particle
and the volume fraction of Mg2Si phase is slightly increased. The optimum particle appearance and refinement can be obtained with about 0. 1% Sb addition
where the size of Mg2Si phase is refined to 25 μm from 52μm. However
excessive Sb content can results in coarsening par-ticle
which means the excessive Sb can detriment the refinement effects. The refinement of Mg2Si phase can be attributed to heterogeneous nucleation resulting from AlSb compound
meanwhile
Sb can decrease liquidus temperature and molten surface tension
which refines the Mg2Si phase to a certain degree too.