CHEN Hong-ling1, FU Gao-sheng1, Yuan Wen-duan1. Refining Effect of a new Al5Ti1B0.5RE Master Alloy on A356 Al Alloy and Role of Rare Earths in the Master Alloy[J]. Special Casting & Nonferrous Alloys, 2008,(S1):161-164.
CHEN Hong-ling1, FU Gao-sheng1, Yuan Wen-duan1. Refining Effect of a new Al5Ti1B0.5RE Master Alloy on A356 Al Alloy and Role of Rare Earths in the Master Alloy[J]. Special Casting & Nonferrous Alloys, 2008,(S1):161-164.DOI:
Al5Ti1B0.5RE中间合金在A356铝合金中的细化效果及RE的作用
摘要
探讨了Al5Ti1B0.5RE中间合金对A356铝合金的细化效果
并用OM、SEM、EDAX等进行微观组织观察分析。结果表明
该中间合金对A356铝合金不仅具有明显的晶粒细化效果
且具有显著的细化枝晶作用;RE对该中间合金的细化效果起到了重要作用
即该中间合金中AlTiRE相在铝液中不稳定
很快被分解释放出RE元素
降低了表面能
减少了TiB2相的聚集倾向
增加了形核粒子的数量;同时RE易吸附偏聚在铝熔体的晶界和相界面上
阻碍TiAl3相的生长
阻止针条状TiAl3相的形成
也增加了成核几率。此外
RE的加入可有效保证该细化剂及铝熔体的冶金质量
在一定程度上也增强了该细化剂的细化效果。
Abstract
The refining effect of Al5Ti1B0.5RE master alloy on A356 Al alloy was studied
and microstructures of A356 Al alloy and the master alloy were analysed by OM、SEM、EDAX etc. The results showed that the master alloy had not only obvious effect of grain refinement
also a significant role in refining dendrite grain of A356 Al alloy. RE elements played an important role in the master alloy
that is
RE could easily form (AlTiRE) phase in the master alloy
but (AlTiRE) phase was unstable in Al melt and could dissolve quickly by releasing RE elements
which deceased the surface energy of Al melt and the tendency of TiB2 particles getting together in Al melt
thus increasing. the number of nuclear particles. Moreover
RE elements could easily get adsorption together between the grain boundary and the phase boundary of Al alloy
thus filling the defects of grain surface
and hindering TiAl3 growing and the formation of needle or strip TiAl3 phase
which increased the nucleation rate on refinement nuclei. Furthermore
RE could effectively guarantee metallurgical quality.of the grain refiner and Al melt
thus also enhancing the effect of the grain refiner.
关键词
铝合金AlTiBRE中间合金稀土晶粒细化微观组织
Keywords
Al AlloyAlTiBRE Master AlloyRare EarthsGrain RefinementMicrostructure