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Effect of Composition on the Hydrogen Storage Characteristics of La0.7Mg0.3Nix Alloy
- Vol. 38, Issue 10, Pages: 1151-1154(2018)
Published: 2018
DOI: 10.15980/j.tzzz.2018.10.028
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Published: 2018 ,
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[1]杨立峰,陆行,肖方敏,朱明.Mg基储氢合金的合金化与储氢性能[J].特种铸造及有色合金,2018,38(10):1151-1154.
Yang Lifeng, Lu Xing, Xiao Fang min, et al. Effect of Composition on the Hydrogen Storage Characteristics of La0.7Mg0.3Nix Alloy. [J]. Special Casting & Nonferrous Alloys 38(10):1151-1154(2018)
采用负压感应熔炼法制备了(La
0.7
Mg
0.3
)Ni
x
(x=2
2.5
3)储氢合金
对比分析了不同组分的快淬和铸锭(La
0.7
Mg
0.3
)Ni
x
储氢合金在退火前后的储氢性能、物相组成和显微形貌。结果表明
随着(La
0.7
Mg
0.3
)Ni
x
合金中Ni含量的增加
快淬储氢合金的放氢平台逐渐升高且变宽
放氢速率和放氢容量逐渐增加
(La
0.7
Mg
0.3
)Ni
2.5
合金的吸放氢平台压力适中;x=2.5时
铸锭储氢合金具有相对x=2时更宽和平整的吸放氢平台
且平台压更高
Ni含量的增加有助于提高(La
0.7
Mg
0.3
)Ni
x
储氢合金的放氢速率;铸锭和快淬(La
0.7
Mg
0.3
)Ni
x
储氢合金在铸态和不同温度退火态下的物相都由LaNi
5
、(LaMg)Ni
3
和(LaMg)
2
Ni
7
相组成
且随着退火温度升高
LaNi
5
和(LaMg)Ni
3
相有朝着(LaMg)
2
Ni
7
相转变的趋势。
The(La
0.7
Mg
0.3
)Ni
x
(x=2
2.5
3)hydrogen storage alloys were prepared by negative pressure induction melting
and the hydrogen storage properties
phase composition and microstructure of rapidly quenched and ingot(La
0.7
Mg
0.3
)Ni
x
hydrogen storage alloys before and after annealing were analyzed comparatively.The results reveal that with the increase of Ni content in(La
0.7
Mg
0.3
)Ni
x
alloy
hydrogen releasing platform of the rapidily quenched hydrogen storage alloy is increased gradually and the platform is tended to be wider
and the rate of hydrogen release and the capacity of the hydrogen release are increased gradually.Plateau pressure of(La
0.7
Mg
0.3
)Ni
2.5
alloy is moderate with relatively better platform performance.When x=2.5
the ingot hydrogen storage alloy has relatively wider and flatten hydrogen absorption and desorption platform compared with hydrogen storage alloy with x=2.In addition
Ni content increase is beneficial to improving the hydrogen releasing rate of the alloy.The phases of ingot and rapidly quenched(La
0.7
Mg
0.3
)Ni
x
hydrogen storage alloys are all composed of LaNi
5
(LaMg)Ni
3
and(LaMg)
2
Ni
7
phases at the as cast and annealed state at different temperatures
and with the increase of annealing temperature
LaNi
5
and(LaMg)Ni
3
phase has the characteristics of transition toward(LaMg)
2
Ni
7
phase.
La-Mg-Ni系合金储氢性能显微形貌
La-Mg-Ni AlloyHydrogen Storage PropertyMicromorphology
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