Li Yinglong, Cao Furong, Chen Yanbo, et al. Liquid-solid Reaction Synthesis Mechanism of Al-Ti-C Grain Refiner. [J]. Special Casting & Nonferrous Alloys (9):592-595(2006)
Li Yinglong, Cao Furong, Chen Yanbo, et al. Liquid-solid Reaction Synthesis Mechanism of Al-Ti-C Grain Refiner. [J]. Special Casting & Nonferrous Alloys (9):592-595(2006)DOI:
Liquid-solid Reaction Synthesis Mechanism of Al-Ti-C Grain Refiner
摘要
通过SEM和TEM等分析手段
研究了液-固反应制备的Al-Ti-C晶粒细化剂合金的组织特征与细化性能
并结合热力学分析
探讨了液-固反应合成机制。结果表明:Al-Ti-C晶粒细化剂合金组织中TiAl3呈枝晶状
TiC呈颗粒状
TiC为非化学计量比化合物
可表示为TiCx形式
x=0.5
0
.8
其晶格常数为0.430
0
.433nm
该晶粒细化剂对纯Al具有良好的组织细化作用;液-固反应中
在液-固界面处形成瞬时高温
从而达到Ti、C反应的热力学条件
Al-Ti-C合金的形成符合溶解-析出机制
并由三组基元反应构成。
Abstract
The microstructure characteristics and refining ability of Al-Ti-C master alloy prepared by liquid-solid reaction were investigated by SEM and TEM
and the liquid-solid synthesized mechanism was analyzed from the view of thermo-kinetics also. The results indicate that the microstructure of the Al-Ti-C master alloy is composed of dendritic TiAl
3
phase and particle TiC
where TiC belongs to non-stoichiometric ratio compound in the form of TiC
x
for x of 0.5
0
.8
whose lattice contant is 0.430
0
.433 nm. The master alloy can obviously refine microstructure of the Al alloy
which is resulted from the occurrence of instantaneous high temperature in the interface of liquid-solid meet the thermal-kinetics conditions of Ti and C reaction during liquid-solid reaction. The formation of Al-Ti-C master alloy belongs to the solution-precipitation mechanisms
which consists of three groups of primitive reactions.