Hou Juncai1, Zhang Qiumei1, Feng Xiao-ming1, et al. Microstructure and Electro-chemical Properties of Mg-Sr Anode. [J]. Special Casting & Nonferrous Alloys (7):560-562(2007)DOI:
Microstructure and Electro-chemical Properties of Mg-Sr Anode
摘要
研究了Mg-Sr牺牲阳极的显微组织和电化学性能的特征。结果表明
Mg-Sr牺牲阳极的晶粒尺寸随Sr含量的增加而减小;当Sr质量分数为0.19%时
电流效率达到58.56%
开路电位达到-1.735VSCE;Sr的质量分数再增加
Mg-Sr阳极的电流效率降低
开路电位正移。研究认为
Sr的质量分数为0.19%时
晶界析出的Mg17Sr2相(弱阴极相)和α-Mg基体(阳极相)组成电偶对
阻碍了阳极晶间腐蚀
减少了晶粒大块脱落
且Sr能够和Mg、Fe形成弱阴极性化合物降低Fe的危害
电流效率升高
同时晶粒细化
晶界面积变大
杂质相分布更均匀
开路电位负移;Sr含量大于0.19%时
过量的Mg17Sr2相作为阴极相加大了阳极的自腐蚀
电流效率下降
开路电位正移。
Abstract
Microstructure and electro-chemical properties of Mg-Sr anode were investigated.The results indicate that the grain size in the Mg-Sr anode can be decreased with the increase of Sr content.The current efficiency and open potential of the anode will reach the peak value of 58.56% and-1.735 Vsce with 0.19% Sr content
while the current efficiency will be decreased and the open potential will be shift positively with the Sr content more than 0.19%.Microgalvanic cell can be formed from Mg17Sr2 phase segregated from boundary and α-Mg phase with 0.19% Sr content
which can inhibit the intergranular corrosion and reduce the grain spallation as well as relieve the deterioration effects of Fe phase to lead to the improvement of current efficiency and the positive shift of open potential as a result of refining grain size and enlarging grain boundary area as well as more uniform inclusion phase distribution.With the Sr content more than 0.19%
excessive Mg12Sr2 phase can increase the self-corrosion rate of the anode
resulting in the decrease of current efficiency and positive shift of open potential.