Wu Zhaogang, Ma Ying, Ma Yuezhou, et al. Effects of NaVO3 on Micro-arc Oxidation Coatings on AZ91D Magnesium Alloys. [J]. Special Casting & Nonferrous Alloys 30(8):761-765(2010)
Wu Zhaogang, Ma Ying, Ma Yuezhou, et al. Effects of NaVO3 on Micro-arc Oxidation Coatings on AZ91D Magnesium Alloys. [J]. Special Casting & Nonferrous Alloys 30(8):761-765(2010)DOI:
Effects of NaVO3 on Micro-arc Oxidation Coatings on AZ91D Magnesium Alloys
摘要
对AZ91D镁合金进行了微弧氧化处理
获得了棕黄色的陶瓷氧化膜层
并研究了不同质量溶度的NaVO3对微弧氧化膜颜色、结构和性能的影响。结果表明
微弧氧化膜层的生长速率随着NaVO3质量溶度的增加逐渐增大
耐蚀性呈先增大后减小的趋势
同时膜层颜色也逐渐变深
但是过量NaVO3的加入不利于反应成膜。EPMA分析表明膜层主要含有Mg、Al、V、O和少量P元素
但含P物相在XRD分析中并没有被检测到
应归因于膜层中P元素含量较少和生成的膜层较薄
使得含P物相在膜层中的沉积量较少。
Abstract
Brown ceramic oxide coatings were prepared on AZ91D magnesium alloys by micro-arc oxidation
and effects of different NaVO3 concentration on the color
microstructure and properties of the coatings were investigated. The results reveal that with increasing in NaVO3 concentration
growth rate of the oxidation coatings is increased
and corrosion resistance of the coating exhibits firstly increase and then decrease
meanwhile
the color of the coatings becomes dark brown gradually. However
excessive NaVO3 concentration is harmful for the micro-oxidation process. EPMA analysis shows that the coating is mainly contained Mg
Al
V
O and little P element
and absence of the phase containing P element can be observed in the XRD
which is attributed to little P content in the coating and thin coatings resulting in the little deposition containing P phase.
State Key Laboratory of Gansu Advanced Non-ferrous Metal Materials, Lanzhou University of Technology,Lanzhou 7300502. Key Laboratory of Non-ferrous Metal Alloys and Processing, The Ministry of Education,Lanzhou University of Technology
兰州理工大学有色金属合金及加工教育部重点实验室
Department of Materials and Chemical Engineering, Xi’an Technological University
School of Mechanical and Power Engineering, Shenyang University of Chemical Technology
School of Mechanical Engineering, Northwestern Polytechnical University