Zhang Qiumei, Hou Juncai. Effects of Mn Content on Microstructure and Electro-chemical Properties of Mg-Mn Sacrificial Anodes. [J]. Special Casting & Nonferrous Alloys 30(12):1166-1168(2010)
Zhang Qiumei, Hou Juncai. Effects of Mn Content on Microstructure and Electro-chemical Properties of Mg-Mn Sacrificial Anodes. [J]. Special Casting & Nonferrous Alloys 30(12):1166-1168(2010)DOI:
Effects of Mn Content on Microstructure and Electro-chemical Properties of Mg-Mn Sacrificial Anodes
摘要
采用高纯镁为原料制备高效Mg-Mn牺牲阳极
探讨了Mn含量分别为0.3%、0.6%、0.8%、1.0%时
对Mg-Mn牺牲阳极显微组织和电化学性能的影响。结果表明
Mn能够有效降低镁熔体中Fe的含量
提高镁阳极的电流效率
但过多的Mn能够和Si、C、O形成相对于α-Mg基体的少量阴极相
加重镁阳极的自腐蚀
使镁阳极的电流效率降低
不同Mn含量的Mg-Mn阳极基体组织均为α-Mg固溶体
Mn含量较低时组织为粗大的柱状晶
增大Mn的含量组织为等轴晶
继续增大Mn含量晶粒细化不明显。
Abstract
Effects of different Mn contents
such as 0.3%
0.6%
0.8% and 1.0%
on the microstructure and electro-chemical properties of the Mg-Mn sacrificial anodes were investigated based on the Mg-Mn anodes with sound electro-chemical properties which were prepared by the highly purified raw magnesium. The results reveal that Mn can effectively reduce Fe content in the magnesium melts and improve the current efficiency of magnesium anodes
however
excessive Mn will decrease the current efficiency of the magnesium anodes due to forming a little secondary phase with Si
C
O as the cathode to promote the self-corrosion of the anodes. The matrix microstructure of the Mg-Mn alloy with different Mn contents is composed of α-Mg solid solution phase which exhibits coarse columnar grain with lower Mn content while it becomes equiaxed grain with increasing in Mn content. However